K. Volynets leads the head-to-head 3-2 since 2018 against T. Maria, over 5 matches.
| Surface | T. Maria | K. Volynets |
|---|---|---|
| Grass | 1 | 1 |
| Hard | 1 | 2 |
| Date | Winner | Score | Event |
|---|---|---|---|
| July 12, 2026 | T. Maria | 2 - 0 | Newport · Final · grass |
| Feb. 3, 2026 | K. Volynets | 2 - 0 | WTA Ostrava · 1/8-finals · hard |
| July 1, 2025 | K. Volynets | 2 - 1 | Wimbledon · 1/64-finals · grass |
| Feb. 1, 2024 | K. Volynets | 2 - 1 | Hua Hin · 1/8-finals · hard |
| Feb. 4, 2022 | T. Maria | 2 - 0 | W60 Rome, GA · Quarter-finals · hard |